个人信息
教师姓名:张永才
教师拼音名称:ZYC
电子邮箱:
入职时间:2003-06-01
所在单位:化学化工学院
职务:professor
学历:博士研究生毕业
办公地点:N111, New Chemistry Building, Yangzhou University, No.180 Siwangting Road, Yangzhou City
联系方式:zhangyc@yzu.edu.cn
学位:博士
职称:副高级
在职信息:在岗
硕士生导师
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所属院系: 化学化工学院
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学科:无机化学
其他联系方式
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论文成果
Efficient photocatalytic reduction of aqueous Cr (VI) by Zr4+ doped and polyaniline coupled SnS2 nanoflakes
发布时间:2023-04-11 点击次数:
DOI码:10.1016/j.seppur.2021.120161
所属单位:扬州大学
教研室:无机教研室
发表刊物:Separation and Purification Technology
关键字:SnS2; Zr4+ doping; PANI coupling; Photocatalytic Cr (VI) reduction; Synergistic effects
摘要:The synergistic Zr4+ doping and PANI coupling were used to improve the photocatalytic activity of SnS2 nanoflakes for the treatment of aqueous Cr (VI). The Zr-SnS2/PANI photocatalyst was prepared by a facile two-step method. The optimal Zr-SnS2/PANI-6% (with the Zr/Sn molar ratio of 1:8 and the PANI content of 6 wt%) exhibited dramatically higher photocatalytic activity toward Cr (VI) reduction than SnS2, Zr-SnS2, SnS2/PANI, and many previously reported SnS2-based and PANI-containing visible-light photocatalysts. Moreover, Zr-SnS2/PANI-6% showed outstanding performance in the photocatalytic treatment of Cr (VI)-containing electroplating solution. Based on the measured photo-electrochemical properties of the samples, the increased photocatalytic efficiency of Zr-SnS2/PANI-6% was mainly due to the synergistic effect induced by the smaller bandgap, higher charge transfer efficiency, and lower electron-hole recombination rate. Furthermore, the effects of coexisting cations and anions, photocatalyst amount, initial pH, Cr (VI) concentration, environmental atmosphere, and co-presence of 1,4-benzoquinone or K2S2O8 on photocatalytic Cr (VI) reduction over Zr-SnS2/PANI-6% were investigated.
论文类型:Research Atricle
论文编号:120161
学科门类:理学
一级学科:化学
文献类型:journal Article
卷号:283
是否译文:否
发表时间:2022-01-15
收录刊物:SCI