个人信息
教师姓名：张永才
教师拼音名称：ZYC
电子邮箱：
入职时间：2003-06-01
所在单位：化学化工学院
职务：professor
学历：博士研究生毕业
办公地点：N111, New Chemistry Building, Yangzhou University, No.180 Siwangting Road, Yangzhou City
联系方式：zhangyc@yzu.edu.cn
学位：博士
职称：副高级
在职信息：在岗
硕士生导师
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所属院系： 化学化工学院
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学科：无机化学
其他联系方式
暂无内容
论文成果
Exceptional synergistic enhancement of the photocatalytic activity of SnS2 by coupling with polyaniline and N-doped reduced graphene oxide
发布时间：2021-06-08 点击次数：
DOI码：10.1016/j.apcatb.2018.05.002
所属单位：扬州大学
教研室：无机教研室
发表刊物：Applied Catalysis B: Environmental
项目来源：江苏省自然科学基金
关键字：Ternary compositeVisible-light-driven photocatalystSynergistic effectsHexavalent chromiumPhotocatalytic reduction mechanisms
摘要：Effective enhancement of the separation and transfer of photogenerated electrons and holes of semiconductor photocatalysts is key to increase their photocatalytic efficiency. This study aims at improving the photocatalytic performance of visible-light-responsive, CdI2-type layered SnS2 by employing good conductivity N-doped reduced graphene oxide (NRG) and polyaniline (PANI) as the receptors and transporters of photogenerated electrons and holes, respectively. PANI/SnS2/NRG ternary composites were prepared by a three-step method, and the optimum conditions for preparing the most efficient product were explored. The photocatalytic experiments demonstrated that the PANI/SnS2/NRG ternary composite prepared under the optimum conditions (PANI/SnS2/NRG-2%) had markedly higher photocatalytic activity than SnS2 nanoplates, SnS2/PANI and SnS2/NRG binary composites in the reduction of aqueous Cr(VI) under the irradiation of visible-light (λ > 420 nm). Based on comparison of the photoabsorption, photoluminescence and electrochemical impedance properties of PANI/SnS2/NRG, SnS2/PANI and SnS2, it was thought that the coupling of SnS2 with both PANI and NRG had synergistic effects in increasing the absorption of visible-light as well as the separation and transfer of photogenerated electrons and holes, which contributed to the exceptionally high photocatalytic activity of PANI/SnS2/NRG ternary composite. Moreover, it was discovered that the photocatalytic reduction of Cr(VI) over PANI/SnS2/NRG-2% was dominantly through the reduction by photogenerated electrons, whereas both photogenerated electron and superoxide anion radical (O2radical dot–) reduction played important roles in the photocatalytic reduction of Cr(VI) over SnS2. Besides, the influences of photocatalytic testing conditions (including starting pH and concentration of Cr(VI) solution, and dosage of photocatalyst) on the efficiency of PANI/SnS2/NRG-2% in treatment of aqueous Cr(VI) were also examined.
论文类型：journalArticle
论文编号：https://doi.org/10.1016/j.apcatb.2018.05.002
学科门类：理学
一级学科：化学
文献类型：journalArticle
卷号：236
页面范围：53-63
是否译文：否
发表时间：2018-11-15
收录刊物：SCI
